Sample | Synthesis conditionsa | Tg (°C) | Tm (°C) | ΔH (J/g) |
---|---|---|---|---|
P(3HP) | Entry 11 |  − 15.0 | 71.9 | 62.3 |
P(3HB) | Entry 10 | 2.4 | 169.0 | 65.9 |
P(55.5 mol% 3HB-co-3HP) | Entry 1 |  − 15.5, 0.8 | 47.9, 161.1 | 7.7, 10.0 |
P(97.1Â mol% 3HB-co-4H2MB) | Entry 6 | 1.1 | 155.9 | 55.5 |
P(95.2 mol% 3HB-co-5HV) | Entry 7 |  − 2.1 | 159.2 | 49.4 |
P(98.3Â mol% 3HB-co-6HHx) | Entry 8 | 0.0 | 162.4 | 59.0 |
P(28.9Â mol% 2HB-co-3HB) | Entry 18 | 3.0 | 163.4 | 28.8 |
P(4.8 mol% 2HB-co-3HP) | Entry 19 |  − 14.6 | 73.2 | 55.1 |
P(4.4 mol% 2HB-co-3HB-co-3HP 55.1 mol%) | Entry 23 |  − 11.8, − 1.3 | 50.3 | 2.3 |
P(26.8Â mol% 2HB-co-3HB-co-4H2MB 2.2Â mol%) | Entry 24 | 2.7 | 159.3 | 35.9 |
P(32.4Â mol% 2HB-co-3HB-co-5HV 3.8Â mol%) | Entry 25 | 2.0 | 163.7 | 30.3 |
P(26.5Â mol% 2HB-co-3HB-co-6HHx 1.1Â mol%) | Entry 26 | 1.7 | 159.4 | 27.6 |