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Table 2 13C NMR chemical shifts of products

From: New 6,19-oxidoandrostan derivatives obtained by biotransformation in environmental filamentous fungi cultures

Atom number

1a

1b

2a

3a

3b

4a

5a

6a

6b

7a

8b

1

23.25

22.84

23.61

23.91

23.30

23.40

25.88

25.73

25.46

19.03

24.95

2

26.99

26.33

30.83

30.89

30.49

30.97

30.87

30.72

30.53

26.44

29.63

3

69.19

68.67

66.41

66.53

64.45

66.34

66.03

66.04

64.27

64.52

63.36

4

40.26

39.66

44.03

44.14

43.84

43.72

44.44

44.69

44.65

48.81

45.80

5

75.67

76.70

76.84

76.31

77.49

75.61

75.83

76.47

77.80

69.50

74.55

6

82.01

80.54

82.08

82.36

80.98

81.76

81.62

81.99

80.85

82.63

80.39

7

31.52

31.29

31.59

31.59

31.45

30.70

31.22

31.25

31.13

28.96

32.53

8

33.05

32.40

33.09

33.60

33.06

35.73

33.37

30.86

30.34

30.81

31.13

9

46.76

46.57

46.92

46.92

46.43

45.64

52.50

53.55

52.91

49.34

52.73

10

45.95

45.27

45.92

45.82

45.11

45.71

81.41

47.64

47.08

46.68

47.56

11

21.81

31.07

21.91

22.15

21.49

23.34

68.72

68.73

66.88

68.42

65.76

12

30.83

30.48

30.91

32.23

32.05

39.32

50.39

43.36

42.83

43.63

42.38

13

48.36

47.70

48.40

46.02

45.39

83.08

47.45

48.62

47.95

48.37

50.50

14

49.57

48.95

49.65

46.93

46.60

44.84

44.10

48.69

48.27

48.78

47.79

15

21.43

20.96

21.49

23.71

23.43

19.55

19.59

21.34

20.91

21.33

20.55

16

35.85

35.28

35.88

32.69

32.08

28.63

28.58

35.94

35.49

35.94

35.42

17

220.26

219.18

220.38

79.71

77.54

171.39

170.90

218.80

218.50

218.64

217.87

18

14.31

13.86

14.33

17.55

17.31

20.47

21.41

15.09

14.63

14.87

14.38

19

68.65

67.62

68.76

68.70

67.70

68.30

69.21

69.74

68.74

101.94

174.95

–COCH3

21.46

21.02

    

–

–

–

  

–COCH3

170.45

169.80

    

–

–

–

  
  1. aDissolved in CDCl3
  2. bIn DMSO-d6