Fig. 5From: Exploiting xylan as sugar donor for the synthesis of an antiproliferative xyloside using an enzyme cascadeDOSY NMR analyses. Signals corresponding to water were used as reference to ease the comparison between both polysaccharides. a Superimposition of DOSY spectra from beechwood xylan (BE-X) in blue and birchwood xylan (BI-X) in red. The x-axis represents chemical shift and the y-axis shows the translational diffusion coefficient. Labels indicate the signals corresponding to the solvent (water) and the weight average of the polysaccharides. b Projection of molecular size distribution of BE-X (blue) and BI-X (red). The x-axis shows the differences at the molecular weight level in terms of translational diffusion coefficient. Labels indicate the peaks corresponding to the polysaccharides and the solvent (water). c Superimposition of the DOSY and 1H 1D spectra of BE-X (blue) and the BI-X (red). Differences in the molecular weight are observed (different diffusion coefficient). Moreover, no acetylation pattern around 2 ppm is observed for both xylans. The peaks at 1.85 ppm/− 9.03 LogD in BI-X and at 1.10 ppm/− 8.98 LogD in BE-X correspond to low molecular weight impurities. The x-axis represents chemical shift and the y-axis shows the translational diffusion coefficientBack to article page