Table 4 13C NMR chemical shifts of products in CDCl3
From: Biotransformation of steroids by entomopathogenic strains of Isaria farinosa
Atom number | Products | |||||
|---|---|---|---|---|---|---|
6β-OH-ADR | 15α-OH-6,7β-epoxy-1-ene-T | 15α-OH-6,7β-epoxy-T | 14α-OH-6,7β-epoxy-1-ene-T | 6β,11α-OH-P | 6β-OH,11-oxo-P | |
1 | 36.10 | 155.97 | 36.28 | 155.69 | 39.11 | 36.15 |
2 | 34.11 | 127.25 | 34.26 | 127.37 | 34.55 | 34.18 |
3 | 200.67 | 185.06 | 198.47 | 184.97 | 201.14 | 200.56 |
4 | 127.17 | 128.97 | 129.70 | 129.36 | 127.17 | 127.24 |
5 | 166.61 | 161.23 | 162.89 | 160.32 | 168.41 | 166.45 |
6 | 72.13 | 56.62 | 58.31 | 56.43 | 73.19 | 72.52 |
7 | 38.10 | 58.51 | 55.68 | 57.24 | 37.66 | 38.94 |
8 | 30.65 | 31.89 | 31.48 | 38.81 | 28.50 | 31.42 |
9 | 63.13 | 51.31 | 52.06 | 44.41 | 59.10 | 62.51 |
10 | 37.68 | 43.70 | 36.93 | 42.02 | 39.39 | 37.97 |
11 | 207.41 | 23.10 | 21.03 | 21.14 | 69.02 | 208.09 |
12 | 50.50 | 37.47 | 37.54 | 30.27 | 50.52 | 56.76 |
13 | 50.44 | 42.68 | 43.39 | 53.38 | 44.40 | 47.02 |
14 | 49.71 | 52.12 | 52.52 | 80.47 | 55.44 | 54.87 |
15 | 21.69 | 68.54 | 68.43 | 24.97 | 24.32 | 24.09 |
16 | 36.03 | 43.49 | 43.41 | 32.93 | 23.14 | 23.49 |
17 | 217.24 | 80.84 | 80.96 | 216.85 | 63.27 | 62.18 |
18 | 14.91 | 13.66 | 13.59 | 18.95 | 14.67 | 14.47 |
19 | 19.32 | 19.00 | 16.95 | 18.67 | 20.33 | 19.20 |
20 | 209.06 | 207.99 | ||||
21 | 31.45 | 31.10 | ||||